Effect of Impurity Scattering on Percolation of Bosonic Islands and Superconductivity in Fe Implanted NbN Thin Films

Nanomaterials (Basel). 2022 Sep 7;12(18):3105. doi: 10.3390/nano12183105.

Abstract

A reentrant temperature dependence of the thermoresistivity ρxx(T) between an onset local superconducting ordering temperature Tloconset and a global superconducting transition at T=Tglooffset has been reported in disordered conventional 3-dimensional (3D) superconductors. The disorder of these superconductors is a result of either an extrinsic granularity due to grain boundaries, or of an intrinsic granularity ascribable to the electronic disorder originating from impurity dopants. Here, the effects of Fe doping on the electronic properties of sputtered NbN layers with a nominal thickness of 100 nm are studied by means of low-T/high-μ0H magnetotransport measurements. The doping of NbN is achieved via implantation of 35 keV Fe ions. In the as-grown NbN films, a local onset of superconductivity at Tloconset=15.72K is found, while the global superconducting ordering is achieved at Tglooffset=15.05K, with a normal state resistivity ρxx=22μΩ·cm. Moreover, upon Fe doping of NbN, ρxx=40μΩ·cm is estimated, while Tloconset and Tglooffset are measured to be 15.1 K and 13.5 K, respectively. In Fe:NbN, the intrinsic granularity leads to the emergence of a bosonic insulator state and the normal-metal-to-superconductor transition is accompanied by six different electronic phases characterized by a N-shaped T dependence of ρxx(T). The bosonic insulator state in a s-wave conventional superconductor doped with dilute magnetic impurities is predicted to represent a workbench for emergent phenomena, such as gapless superconductivity, triplet Cooper pairings and topological odd frequency superconductivity.

Keywords: bosonic insulator; implantation; percolation.