Upcycling Discarded Shoe Polish into High Value-Added Asphalt Fluxing Agent for Use in Hot Mix Paving Applications

Materials (Basel). 2022 Sep 17;15(18):6454. doi: 10.3390/ma15186454.

Abstract

This research effort is geared towards revealing the latent potential of discarded shoe polish that might be repurposed as an asphalt fluxing agent for the construction of durable and sustainable road surfaces. To drive this creative invention, the effect of various proportions of waste shoe polish (e.g., 5, 10 and 15 wt. % WSP) on the performance of base AP-5 bitumen was inspected in great detail. A meticulous investigation of the chemical, physical, and rheological properties of the resultant combinations was carried out using a variety of state-of-the-art laboratory techniques, specifically: thin-layer chromatography-flame ionization detection (TLC-FID), Fourier transform-infrared spectroscopy (FT-IR), needle penetration, ring-and-ball softening point, Brookfield viscometer, ductility, flash/fire points, dynamic shear rheometer (DSR), multiple stress-creep recovery (MSCR), and bending beam rheometer (BBR) tests. The Iatroscan data disclosed that the continuous feeding of binder with WSP had a minor impact on SARA fractional distribution, regardless of aging. According to the FT-IR scan, the stepwise addition of WSP to the binder did not result in any significant chemical alterations in the blends. The combined outcomes of the DSR/BBR/empirical test methods forecasted that the partly bio-sourced additive would greatly improve the mixing-compaction temperatures, workability, and coating-adhesion properties of bituminous mixtures while imparting them with outstanding anti-aging/cracking attributes. In short, the utilization of waste shoe polish as a fluxing agent for hot asphalt mix production and application is not only safe, feasible, and affordable, but it has the potential to abate the pollution caused by the shoe-care market while simultaneously enhancing the overall performance of the pavement and extending its service lifespan.

Keywords: BBR; DSR; FT-IR; MSCR; TLC-FID; discarded shoe polish; empirical tests; flash point; fluxing agent; hot mix asphalt.

Grants and funding

This study was conducted under the Research Project (22POQW-C152690-04) funded by the Ministry of Land, Infrastructure, and Transport (MOLIT) and the Korea Agency for Infrastructure Technology Advancement (KAIA). This work was also partially supported by the Education and Research Promotion Program of KOREATECH in 2022.