Due to the finite nature, health and environmental hazards currently associated with the use of fossil energy resources, there is a global drive to hasten the development and deployment of renewable energy technologies. One such area encompasses perovskite solar cells (PSCs) that have shown photoconversion efficiencies (PCE) comparable to silicon-based photovoltaics, but their commercialisation has been set back by short-term stability and toxicity issues, among others. A tremendous potential to overcome these drawbacks is presented by the emerging applications of graphene derivative-based materials in PSCs as substitutes or components, composites with other functional materials, and enhancers of charge transport, blocking action, exciton dissociation, substrate coverage, sensitisation and stabilisation. This review aims to illustrate how these highly capable carbon-based materials can advance PSCs by critically outlining and discussing their current applications and strategically identifying prospective research avenues. The reviewed works show that graphene derivatives have great potential in boosting the performance and stability of PSCs through morphological modifications and compositional engineering. This can drive the sustainability and commercial viability aspects of PSCs.
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