Conventional optical anti-counterfeiting strategies are based on the single-color emission, which are easily deciphered and thus greatly limited in the application of information security. Herein, a multimodal dynamic optical information coding with red, green, and blue (RGB) tricolors has been developed by photoluminescence (PL), persistent luminescence (PersL), thermally stimulated luminescence (TSL), and thermally stimulated persistent luminescence (TSPL). The BaSi2O2N2:Eu2+ phosphors with a blue emission peak at 494 nm were used as the crucial blue optical information coding material and exhibited the distinctive response properties to light, heat, and force stimuli with intrinsic trap depths of 0.674 and 0.82 eV. More importantly, by combining the red Sr2Si5N8:Eu2+,Dy3+ and green SrSi2O2N2:Eu2+,Dy3+ nitride phosphors, a RGB tricolor and multimodal strategy has been successfully developed for anti-counterfeiting applications. The "RGB tricolor flower" with RGB emissions is given as a typical example to achieve the dynamic display of optical information encryption and decoding through the various PL, PersL, TSL, and TSPL modes. Finally, the traditional quick response (QR) code mechanism has been integrated into the design of multi-information encrypted RGB tricolor anti-counterfeiting devices with different identifiabilities of the encrypted information in natural light, PL, PersL, TSL, and TSPL modes. The laminated layers of RGB QR code patterns containing different specific information, such as "DLPU" and "116034", can be effectively recognized in the corresponding modes. The design strategy of RGB tricolor and multimodal optical information encryption and decoding devices in this work greatly improves the security level of advanced optical information technologies and extends the potential applications in dynamic anti-counterfeiting fields.
Keywords: RGB tricolor; anti-counterfeiting; encryption; nitride phosphor; optical information storage.