Environmental application of a cost-effective smartphone-based method for COD analysis: Applicability in the electrochemical treatment of real wastewater

Abstract

This study aims to develop a cheap method for the evaluation of quality of water or the assessment of the treatment of water by chemical oxygen demand (COD) measurements throughout the use of the HSV color model in digital devices. A free application installed on a smartphone was used for analyzing the images in which the colors were acquired before to be quantified. The proposed method was also validated by the standard and spectrophotometric methods, demonstrating that no significant statistical differences were attained (average accuracy of 97 %). With these results, the utilization of this smartphone-based method for COD analysis was used/evaluated, for first time, by treating electrochemically a real water matrix with substantial organic and salts content using BDD and Pt/Ti anodes. Aiming to understand the performance of both anodes, bulk experiments were performed under real pH by applying current densities (j) of 15, 30, and 60 mA cm^-2. COD abatement results (which were achieved with this novel smart water security solution) clearly showed that different organic matter removal efficiencies were achieved, depending on the electrocatalytic material used as well as the applied current density (42 %, 45 %, and 85 % for Ti/Pt while 93 %, 97 % and total degradation for BDD by applying 15, 30, and 60 mA cm^-2, respectively). However, when the persulfate-mediated oxidation approach was used, with the addition of 2 or 4 g Na₂SO₄ L^-1, COD removal efficiencies were enhanced, obtaining total degradation with 4 g Na₂SO₄ L^-1 and by applying 15 mA cm^-2. Finally, this smartphone imaging-based method provides a simple and rapid method for the evaluation of COD during the use of electrochemical remediation technology, developing and decentralizing analytics technologies for smart water solutions which play a key role in achieving the Sustainable Development Goal 6 (SDG6).

Keywords: Chemical oxygen demand; Digital image colorimetry; Electrochemical oxidation; Smartphone-based technology; Sustainable Development Goal; Wastewater treatment.