Integrating structural anisotropy, excellent mechanical properties, and superior sensing capability into conductive hydrogels is of great importance to wearable flexible electronics yet challenging. Herein, inspired from the aligned structure of human muscle, we proposed a facile and universal method to construct an anisotropic hydrogel composed of polyacrylamide and sodium alginate by pre-stretching in a confined geometry and subsequent ionic cross-linking. The designed hydrogels showed extraordinary mechanical performances, such as ultrahigh stretchability, a comparable modulus to that of human tissues, and good toughness, ascribed to their anisotropically aligned polymer networks. Additionally, the hydrogel possessed anisotropic conductivity due to the anisotropy in ion transport channels. The hydrogel along the vertical direction was further cut and assembled into a flexible strain sensor, exhibiting a low detection limit (0.1%), wide strain range (1585%), rapid response (123 ms), distinct resilience, good stability, and repeatability, thereby being capable of monitoring and discriminating different human movements. In addition, the relatively high ionic conductivity and superior sensitivity enabled the anisotropic hydrogel sensor to be used for wireless human-machine interaction. More interestingly, the Ca2+-cross-linking strategy also endowed the hydrogel sensor with antifreezing ability, further broadening their working temperature. This work is expected to speed up the development of hydrogel sensors in the emerging wearable soft electronics.
Keywords: anisotropic hydrogels; antifreezing performance; conductive hydrogels; strain sensor; wireless transmission.