Displays and indicators are an integral component of everyday electronics. However, the short lifecycle of most applications is currently contributing to the unsustainable growth of electronic waste. In this work, we utilize ecofriendly materials in combination with sustainable processing techniques to fabricate inkjet-printed, ecofriendly dual-mode displays (DMDs). These displays can be used in a reflective mode or an emissive mode by changing between DC and AC operation due to the combination of an electrochromic (EC) and electrochemiluminescent (ECL) layer in a single device. The EC polymer poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) serves as the reflective layer, while an ECL gel made of dimethylsulfoxide (DMSO), poly(lactic-co-glycolic acid) (PLGA), 1-butyl-3-methylimidazoliumbis(oxalato)borate (BMIMBOB), and tris(bipyridine)ruthenium(II) chloride (Ru2+(bpy)3Cl2) enables the emissive mode. The final dual-mode devices exhibited their maximum optical power output of 52 mcd/m2 at 4 V and 40 Hz and achieved an EC contrast of 45% and a coloration efficiency of 244 cm2/C at a wavelength of 690 nm. The fabricated devices showed clear readability in dark and light conditions when operated in reflective or emissive modes. This work demonstrates the applicability of ecofriendly and potentially biodegradable materials to reduce the amount of hazardous components in versatile display technologies.
Keywords: dual-mode device; ecofriendly materials; electrochemiluminescent devices; electrochromic devices; inkjet printing.