Removal of ofloxacin from water by natural ilmenite-biochar composite: A study on the synergistic adsorption mechanism of multiple effects

Abstract

The preparation cost is one of the major constraints for adsorbent applied to practical situations. Here, a novel, economical and eco-friendly ilmenite biochar composite (ILM-BC) was successfully prepared by co-cracking of natural ilmenite and corn stover for the removal ofloxacin from water. The adsorption experiments indicated that the removal ofloxacin by ILM-BC was chemisorption and belonged to a spontaneous and entropy-increasing heat absorption process. Among composites, ILM-BC5 had superior adsorption capacity and stability, with a removal rate 1.6 times higher than that of biochar, and it could remove more than 90% ofloxacin in the pH range of 2-10. Multiple characterization results indicated that the adsorption of ILM-BC was the result of the synergistic effect of pore filling, hydrogen bonding, and π-π interactions. The introduction of ilmenite promoted hydrogen bonding formation and π-π interactions by enriching -OH and -COO on the surface of ILM-BC, which could enhance the adsorption capacity of ILM-BC.

Keywords: Adsorption; Natural ilmenite-biochar composite; Ofloxacin; Removal mechanisms.