This study demonstrates the first reported thermocatalytic oxidation of an indoor volatile organic compound (VOC), acetaldehyde, by harnessing the waste-heat energy from indoor light sources (e.g., halogen lamps) without additional energy inputs. With an optimal Pt-TiO2 catalyst, the designed catalyst-coated lampshade was successfully activated under waste-heat energy (∼120 °C) and achieved the complete mineralization of CH3CHO into CO2 (k = 0.02 min-1). The catalytic activity of Pt-TiO2 was extremely dependent on its preparation method which greatly influenced the characteristics (e.g., oxidation state and size) of Pt. The thermocatalytic oxidation mechanism of CH3CHO over Pt-TiO2 was investigated, which revealed that O2 and H2O sources play vital roles. Although Pt is an expensive noble metal, the thermocatalytic process on the Pt-TiO2-coated lampshade without additional energy, along with its outstanding activity, can offset the high material cost. The proposed strategy offers a sustainable and feasible method for the degradation of indoor VOCs.
Keywords: Acetaldehyde; Low-temperature catalyst; Mineralization; Thermocatalytic oxidation; Waste-heat energy.
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