On spot detection of nickel and cobalt from exhausted batteries by a smart electrochemical sensor

Abstract

This work presents the realization and the application of an user-friendly electrochemical platform based on screen-printed electrodes for the simultaneous determination of nickel and cobalt ions in real samples by means of square wave adsorptive stripping voltammetry (SWAdSV). The sensor was realized by electrodepositing in situ a bismuth film onto graphite screen-printed electrodes (GSPEs). The sensor surface was fully characterized by scanning electron microscopy (SEM), cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The experimental conditions for the determination of nickel and cobalt in the form of dimethylglyoximate complexes were studied and optimized. Linear calibration curves for Ni(II) and Co(II), determined individually and together, in the range 10-40 μg/L for nickel and 10-60 μg/L for cobalt, respectively, were obtained. The limits of detection for nickel and cobalt determination were 2.5 μg/L and 2.4 μg/L, respectively. The performance of the sensor in terms of reproducibility and selectivity was also studied. The applicability of the developed platform was assessed by determining nickel and cobalt in samples deriving from an industrial process of recycling exhausted batteries and in soil samples.

Keywords: Batteries recycling; Cobalt; Nickel; On-site detection; Stripping voltammetry.