Concentrations of perfluoroalkyl and polyfluoroalkyl substances before and after full-scale landfill leachate treatment

Abstract

Many consumer and industrial products, industrial wastes and dewatered sludge from municipal wastewater treatment plants containing per- and polyfluoroalkyl substances (PFAS) are disposed of in landfills at the end of their usage, with PFAS in these products leached into landfill leachates. On-site leachate treatment is one possible method to reduce PFAS in leachates. Many landfills are equipped with on-site leachate treatment systems, but few full-scale facilities have been systematically evaluated for PFAS concentration changes. The objective of this study was to evaluate a cross-section of full-scale on-site landfill treatment systems to measure changes in PFAS concentrations. Leachate samples were collected before and after treatment from 15 facilities and were evaluated for 26 PFAS, including 11 perfluoroalkyl carboxylic acids (PFCAs), 7 perfluoroalkyl sulfonic acids (PFSAs), and 8 perfluoroalkyl acid precursors (PFAA-precursors). Transformation of precursors was evaluated by the total oxidizable precursor (TOP) assay. Results showed no obvious reductions in total measured PFAS (∑₂₆PFAS) for on-site treatment systems including ponds, aeration tanks, powdered activated carbon (PAC), and sand filtration. Among evaluated on-site treatment systems, only systems fitted with reverse osmosis (RO) showed significant reductions (98-99 %) of ∑₂₆PFAS in the permeate. Results from the TOP assay showed that untargeted PFAA-precursors converted into targeted short-chain PFCAs increasing ∑₂₆PFAS in oxidized samples by 30 %, on average. Overall, results of this study confirm the efficacy of RO systems and suggest the presence of additional precursors beyond those measured in this study.

Keywords: Leachate treatment; PFAA-precursors; PFAS; PFOA and PFOS; TOP assay.