The development of safety sensors is an urgent necessity for the successful use of hydrogen in real conditions, which may differ, in particular, by the oxygen content in the surrounding atmosphere. Palladium-modified zinc oxide shows the high sensitivity when detecting hydrogen in air; however, studies of the sensor properties and the operation mechanism of the ZnO/Pd sensor when reducing gases are detected in an oxygen deficient or inert atmosphere have not been effectuated. In this work, we synthesized the ZnO and ZnO/Pd nanofibers by electrospinning and for the first time determined their sensor properties in the detection of CO, NH3 and H2 in different oxygen backgrounds. The microstructure and composition of nanofibers were characterized by electron microscopy, X-ray diffraction, X-ray fluorescent spectroscopy, and X-ray photoelectron spectroscopy. The interaction with the gas phase was investigated in situ by diffuse reflectance IR Fourier transform spectroscopy (DRIFTS). The sensor properties of ZnO and ZnO/Pd nanofibers were studied at 100-450 °C towards CO, NH3 and H2 in the N2/O2 gas mixtures containing 0.0005-20% O2. When detecting CO, a decrease in the oxygen concentration from 20 to 0.0005% in the gas phase does not lead to a significant change in the sensor response. At the same time, when detecting NH3 and especially H2, a decrease in oxygen concentration down to 0.0005% results in the dramatic increase in the sensor response of ZnO/Pd nanofibers. This result is discussed in terms of palladium hydride formation, modulation of the potential barrier at the ZnO/Pd interface, as well as changes in the concentration of donor defects and charge carriers in the ZnO matrix. Synthesized electrospun ZnO/Pd nanofibers are extremely promising materials for sensors for detecting hydrogen in an oxygen free atmosphere.
Keywords: Pd clusters; different oxygen backgrounds; electrospinning; hydrogen; nanofibers; semiconductor gas sensor; zinc oxide.