Superhydrophobic microrobots that can swim efficiently and rapidly on water under the action of external stimuli have attracted significant research attention for various applications. However, most studies on superhydrophobic microrobots have focused on single-stimulus driving modes, which limit the motion and functional applications of microrobots in complex aquatic environments. Therefore, multistimuli-responsive superhydrophobic microrobots that are capable of drifting rapidly on water through light, magnetic, and chemical control were developed in this study. The stability and environmental adaptability of the microrobots were systematically investigated. The microrobots achieved programmable trajectory motion on water, particularly complex motions such as circular, spiral, and helical movements under the coupled influence of chemical and magnetic fields. Importantly, the motion and control of multimicrorobots can be realized by combining control methods. Under the action of light and magnetic field, multimicrorobots could realize cooperative movement and completed the transportation of cargo. Additionally, broad multifunctional applications of the microrobots were explored in terms of oil spill recovery and solution mix. This study provides a method for the preparation and development of superhydrophobic microrobots with multistimuli-responsive characteristics.
Keywords: biomimetic; graphene; microrobots; multistimuli-responsive; superhydrophobic.