Mechanistic and Kinetic Investigations of ON/OFF (Photo)Switchable Binding of Carbon Monoxide by Chromium(0), Molybdenum(0) and Tungsten(0) Carbonyl Complexes with a Pyridyl-Mesoionic Carbene Ligand

Pit J Boden; Patrick Di Martino-Fumo; Tobias Bens; Sophie T Steiger; Daniel Marhöfer; Gereon Niedner-Schatteburg; Biprajit Sarkar

doi:10.1002/chem.202202543

Mechanistic and Kinetic Investigations of ON/OFF (Photo)Switchable Binding of Carbon Monoxide by Chromium(0), Molybdenum(0) and Tungsten(0) Carbonyl Complexes with a Pyridyl-Mesoionic Carbene Ligand

Chemistry. 2022 Sep 12;28(51):e202202543. doi: 10.1002/chem.202202543. Epub 2022 Sep 1.

Authors

Pit J Boden¹, Patrick Di Martino-Fumo¹, Tobias Bens², Sophie T Steiger¹, Daniel Marhöfer¹, Gereon Niedner-Schatteburg¹, Biprajit Sarkar²

Affiliations

¹ Department of Chemistry and State Research Center Optimas, TU Kaiserslautern, Erwin-Schrödinger-Straße 52, 67663, Kaiserslautern, Germany.
² Chair of Inorganic Coordination Chemistry, Institute of Inorganic Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569, Stuttgart, Germany.

PMID: 36047987
DOI: 10.1002/chem.202202543

Abstract

Invited for the cover of this issue are Gereon Niedner-Schatteburg, Biprajit Sarkar and co-worker at TU Kaiserslautern and the University of Stuttgart. The image depicts the selective dissociation of an axial CO from a metal complex. Read the full text of the article at 10.1002/chem.202201038.