Crosslinking plays a crucial role in determining mechanical properties of polymer materials. Although various crosslinks based on covalent or noncovalent bonds have been adopted, it remains an enormous challenge to develop a crosslink which could endow corresponding polymer network with robust yet dynamic properties. Herein, we report a crosslink simultaneously having dynamic property and woven geometry, and the polymer network with woven crosslinks (WPN) could integrate the merits of covalent polymer network (CPN) and supramolecular polymer network (SPN). In specific, the WPN not only exhibits comparable stiffness, strength, elastic recovery, and anti-fatigue property to those of CPN, but also possesses decent mechanical adaptivity and ductility, similar to those of SPN. Particularly, its toughness and puncture resistance are much superior to those of the others. Besides, the dynamicity of woven crosslink also imparts good performances of self-healing and processability to WPN.
Keywords: Dynamic Materials; Mechanical Adaptivity; Metal Coordination; Polymer Networks; Woven Crosslinks.
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