The long reaction time and uncontrollable reaction process of the swelling agent in the process of rock breaking by static crushing agent lead to unsatisfactory efficiency and effect of rock breaking. This paper uses physical experiments to compare and analyze the changes in temperature and pressure of the hydration reaction under different microwave conditions; utilizes microscopic analysis of the hydration reaction products under each condition, combined with numerical calculations to elucidate the mechanism of the effect of microwave field on the hydration reaction of the expansion agent; and proposes a microwave field-controlled static crushing agent rock-breaking method. The study reached the following main conclusions: (1) microwave heating is better than conventional heating in terms of heating rate, peak temperature, and peak pressure; (2) using static crushing agent rock breaking is preferable to use a low-power microwave field to control the reaction process, and to ensure that the initial temperature is not higher than the local water boiling point; (3) microwave heating to promote the reaction mechanism lies in its deep heating of the system, faster heating rate, and higher energy utilization, and is more conducive to hydration expansion reaction; (4) selective heating of microwaves can enhance the hydration reaction of calcium oxide and inhibit the production of hydrated tricalcium silicate, making the reaction more complete, while microwave heating will also improve the microstructure of hydration products.
© 2022 The Authors. Published by American Chemical Society.