Treatment of cadmium and zinc-contaminated water systems using modified biochar: Contaminant uptake, adsorption ability, and mechanism

Abstract

Cd and Zn contamination in water occurs frequently that threatens water supply, human health, and food production. MnFeB, a novel absorbent biochar modified using KMnO₄ and hematite, was prepared and used for the treatment of Cd²⁺ and Zn²⁺solutions. MnFeB exhibits a rough surface structure, large specific surface area, higher total pore volume, massive functional groups, and abundant iron oxide, all of which contribute to higher Cd²⁺ and Zn²⁺ adsorption capacity. In single metal systems, maximum Cd²⁺ and Zn²⁺ adsorption capacities of MnFeB were 1.88 and 1.79 times higher than those of unmodified biochar (CSB). The maximum Cd²⁺ and Zn²⁺ adsorption capacities of MnFeB were 2.73 and 2.65 times higher than CSB in the binary metal system. Key adsorption mechanisms of Cd²⁺ and Zn²⁺ by MnFeB included electrostatic interaction, co-precipitation, π-π interaction, complexation, and ion exchange. Thus, MnFeB can be used as a novel absorbent to treat Cd and Zn-polluted water.

Keywords: Adsorption mechanism; Biochar modification; Competitive adsorption; Heavy metal; Water pollution.