Selective reduction of nitrite to nitrogen by polyaniline-carbon nanotubes composite at neutral pH

Abstract

The selective reduction of nitrite (NO₂^-) to nitrogen by chemical reductant is a desirable strategy to remove NO₂^- from polluted water and wastewater. However, the residue and reuse of chemical reductant are two main issues to be addressed. Herein, a novel polyaniline-carbon nanotubes composite (PANI-CNTs) was developed by in-situ polymerization to selectively reduce NO₂^- to nitrogen gas (N₂). The used PANI-CNTs could be reused after regeneration with NaBH₄. The PANI-CNTs could reduce NO₂^- with 93.9% N₂ selectivity at initial pH of 6.8. The NO₂^- removal efficiency only decreased by 12.08% after five cycles of reduction/regeneration. The interconversion between imine nitrogen (-N) and amine nitrogen (-NH-) groups induced the chemical reduction of NO₂^- and regeneration of PANI-CNTs. PANI-CNTs exhibited an excellent performance for the removal of NO₂^- in the presence of competitive ions and in actual water and wastewater samples. This new PANI-CNTs composite may have great potential for water purification and wastewater denitrification.

Keywords: Chemical reduction; Denitrification; Nitrite; Polyaniline-based composite.