Recently, flexible sensors have gained significant attention due to their potential applications in soft robotics and biomimetic intelligent devices. However, the successful production of favorable flexible sensors integrated with high flexibility, sensitivity and excellent environment adaptability toward multiple external stimuli is still an enormous challenge. Herein, a lightweight polymeric porous sponge capable of detecting an external magnetic field and strain excitations is proposed by assembling a sodium alginate/chitosan (SA/CHI) porous sponge with micron carbonyl iron and nanoscale Fe3O4 magnetic particles (MPs). Based on the double network structure, the SA/CHI sponge possesses preferable mechanical strength and hydrophilicity, demonstrating its high flexibility and deformability. More importantly, the electrical response of the SA/CHI sponge sensors can display remarkable variation under external magnetic and mechanical stimuli due to their superior magnetic characteristics and electrical conductivity. Meanwhile, their sensing properties can maintain relatively stable recoverability and repeatability towards the periodic excitations and releases. Additionally, a potential mechanism is provided to investigate their stimuli-sensitive behavior. It is highly dependent on the microstructure variations in MPs and conductive multi-walled carbon nanotube (MWCNTs) networks. Due to its exceptional magnetic controllability and appropriate electrical sensitivity, the proposed sensor shows high potential in wearable multi-sensing electronics and intelligent transport devices.
Keywords: electrical response; flexible sensors; mechanical properties; micron and nanoscale magnetic particles; multi-sensing mode; polymeric porous sponge.