Customizing the Appearance of Sparks with Binary Metal Alloys

ACS Omega. 2022 Aug 1;7(32):28408-28420. doi: 10.1021/acsomega.2c03081. eCollection 2022 Aug 16.

Abstract

Long-flying sparks are an essential part of several pyrotechnic effects. Unfortunately, and in contrast to colored flames, the color space of sparks is basically limited to the black body curve. With low-boiling-point metals, vapor-phase combustion and bright colorful flashes are achievable. Since 1999, alloys of rare-earth elements have been proposed for colorful spark generation. To the best of our knowledge, here, we present the first investigation of such alloys to change the color of sparks beyond the black body limit. Alloys consisting of >65 at. % of a brightly emitting and low-boiling-point metal and a carrier metal allow achieving long-flying deeply colored sparks. Besides the color, branching of sparks is crucial for the visual appearance. Rare-earth metals were found to promote branching of different alloys. Finally, fountains ejecting golden/green sparks based on a stable eutectic Yb-Cu alloy and continuously branching sparks based on Nd2Fe14B are presented.