Single-atom site catalysts for environmental remediation: Recent advances

Abstract

Single-atom site catalysts (SACs) can maximize the utilization of active metal species and provide an attractive way to regulate the activity and selectivity of catalytic reactions. The adjustable coordination configuration and atomic structure of SACs enable them to be an ideal candidate for revealing reaction mechanisms in various catalytic processes. The minimum use of metals and relatively tight anchoring of the metal atoms significantly reduce leaching and environmental risks. Additionally, the unique physicochemical properties of single atom sites endow SACs with superior activity in various catalytic processes for environmental remediation (ER). Generally, SACs are burgeoning and promising materials in the application of ER. However, a systematic and critical review on the mechanism and broad application of SACs-based ER is lacking. Herein, we review emerging studies applying SACs for different ERs, such as eliminating organic pollutants in water, removing volatile organic compounds, purifying automobile exhaust, and others (hydrodefluorination and disinfection). We have summarized the synthesis, characterization, reaction mechanism and structural-function relationship of SACs in ER. In addition, the perspectives and challenges of SACs for ER are also analyzed. We expect that this review can provide constructive inspiration for discoveries and applications of SACs in environmental catalysis in the future.

Keywords: Advanced oxidation processes; Catalytic oxidation; Environmental remediation; Photocatalytic degradation; Single-atom site catalysts.