Removal assessment of disinfection by-products (DBPs) from drinking water supplies by solar heterogeneous photocatalysis: A case study of trihalomethanes (THMs)

Abstract

Solar heterogeneous photocatalysis was used to remove trihalomethanes (THMs) from drinking water. THMs, mainly trichloromethane (TCM), tribromomethane (TBM), bromodichloromethane (BDCM) and dibromochloromethane (DBCM) are one of the main class of disinfection by-products (DBPs). THMs were determined by HSGC-MS with detection limits (LODs) ranging from 0.5 μg L^-1 to 0.9 μg L^-1 for TCM and BDCM, respectively. Results show that a great proportion of THMs present in water are finally transferred to air as a result of their high volatility in the order TCM > BDCM > DBCM > TBM. The use of band-gap semiconductor materials (TiO₂ and mainly ZnO) used as photocatalysts in combination with Na₂S₂O₈ as electron acceptor and sulfate radical anion (SO₄^•-) generator enhanced the photooxidation of all THMs as compared to photolytic test. The time required for 50% of THMs to disappear (DT₅₀) from water calculated for the most effective treatment (ZnO/Na₂S₂O₈) were 12, 42, 57 and 61 min for TCM, TBM, BDCM, and DBCM, respectively. Therefore, solar heterogeneous photocatalysis can be considered as an interesting strategy for THMs removal, especially in sunny areas like Mediterranean basin.

Keywords: Bromodichloromethane; Bromoform; Chloroform; Dibromochloromethane; Natural sunlight.