The performance degradation of oil caused by moisture and water pollution induced by the infiltration of oil can result in huge losses for society. This is especially true of stable emulsified mixtures of oil and water, which are difficult to separate and urgently require a processing method. In this work, a robust Janus membrane prepared by combining simple electrodeposition and spraying processes was used to separate water-in-transformer oil/lubricating oil emulsions and various oil-in-water emulsions. The membrane with outstanding separation efficiency was also endowed high flux to emulsions, even after 10 separation cycles and 100 sand impact tests, indicating that separation ability was retained. Furthermore, the excellent resistance to acidic and alkaline liquids of the superhydrophobic side groups of the membrane increased the possibility of its service in harsh environments. This study's findings reveal great potential regarding the expansion and application of oil-water separation materials.