Synthesis and crystal structure of hydrated μ-oxa-lato-bis-{bis-[3-methyl-5-(pyridin-2-yl)-1 H-1,2,4-triazole]iron(II)} bis-(toluene-sulfonate) 2.75-hydrate

Yuliia P Petrenko; Yurii S Bibik; Dmytro M Khomenko; Roman O Doroshchuk; Il'ya A Gural'skiy; Sergiu Shova; Rostyslav D Lampeka; Ilona V Raspertova

doi:10.1107/S2056989022007460

Synthesis and crystal structure of hydrated μ-oxa-lato-bis-{bis-[3-methyl-5-(pyridin-2-yl)-1 H-1,2,4-triazole]iron(II)} bis-(toluene-sulfonate) 2.75-hydrate

Acta Crystallogr E Crystallogr Commun. 2022 Jul 26;78(Pt 8):829-832. doi: 10.1107/S2056989022007460. eCollection 2022 Aug 1.

Authors

Yuliia P Petrenko¹, Yurii S Bibik¹, Dmytro M Khomenko^{1

2}, Roman O Doroshchuk^{1

2}, Il'ya A Gural'skiy¹, Sergiu Shova³, Rostyslav D Lampeka¹, Ilona V Raspertova¹

Affiliations

¹ Department of Chemistry, Kyiv National Taras Shevchenko University, Volodymyrska, st. 64, Kyiv, Ukraine.
² Enamine Ltd., Chervonotkatska Street 78, Kyiv 02094, Ukraine.
³ "Petru Poni" Institute of Macromolecular Chemistry, Aleea Gr. Ghica, Voda 41A, 700487 Iasi, Romania.

Abstract

In the title compound [Fe₂(C₂O₄)(C₈H₈N₄)₄](CH₃C₆H₄SO₃)₂·2.75H₂O, the two Fe^II ions have a highly distorted octa-hedral FeN₄O₂ environment formed by two bidentate triazole-based chelating ligands and a bis-bidentate oxalate bridging anion that connects the metal ions. Stabilization within the crystal structure is provided via a system of O-H⋯O and N-H⋯O hydrogen bonding, which determines the formation of a two-dimensional architecture along the a-axis direction.

Keywords: 1,2,4-triazole; X-ray crystallography; crystal structure; iron(II) complex; oxalato-bridged complex.

Grants and funding

This work was supported by grants 22BF037–06 obtained from the Ministry of Education and Science of Ukraine.