Abundance and characteristics of sediment-bound magnetic minerals and trace elements in karst ditch wetland: A case study from Guizhou Province, China

Ecotoxicol Environ Saf. 2022 Sep 15:243:113963. doi: 10.1016/j.ecoenv.2022.113963. Epub 2022 Aug 12.

Abstract

This study investigated sediment-bound magnetic properties and selected trace elements level in the karst ditch wetland, Caohai National Nature Reserve, Guizhou Province, China. Sediment-bound magnetic signals were quantified using low-frequency mass magnetic susceptibility (χLF), anhysteretic remanent magnetization susceptibility (χARM), saturation isothermal remanent magnetization (SIRM), and percentage frequency-dependent susceptibility (χfd%). Concentrations of Cd, Cr, Sb and Zn were determined using inductively coupled plasma mass spectrometry. Sediment χLF, χARM, SIRM, and χfd% were higher than those of bedrocks and mainly altered by the pedogenic processes. The estimated χfd% ranged from 6.15 % to 14.62 % and reflected the magnetic grain sizes were largely concentrated in the range of superparamagnetic particles. The elevated concentrations of sediment-bound Cd, Cr, Sb, and Zn supported the significant contribution of the anthropogenic sources in the karst ditch wetlands. The weak relationship between magnetic signals and selected trace elements (p < 0.05) suggested the occurrence of few sediment-bound iron-containing minerals associated with selected trace elements. These results indicated that a minor contribution of anthropogenic sources of selected trace elements to the elevated sediment magnetic signals in the karst ditch wetlands.

Keywords: Ditch wetland; Karst; Magnetic properties; Trace elements.

MeSH terms

  • Cadmium / analysis
  • China
  • Environmental Monitoring / methods
  • Geologic Sediments / chemistry
  • Magnetic Phenomena
  • Metals, Heavy* / analysis
  • Minerals / analysis
  • Trace Elements* / analysis
  • Water Pollutants, Chemical* / analysis
  • Wetlands

Substances

  • Metals, Heavy
  • Minerals
  • Trace Elements
  • Water Pollutants, Chemical
  • Cadmium