Investigation of the chemical and radiation stability of titanium dioxide with surface arsenate groups during 90Sr adsorption

Abstract

The chemical and radiation stability of titanium dioxide with surface arsenate groups during ⁹⁰Sr adsorption has been studied. The oxalate technique has been used to obtain a solution containing ⁹⁰Sr from the objects of the aquatic environment of the Chornobyl Exclusion Zone. The dependence of the strontium adsorption on the acidity of the solution and the initial activity of the solution (Bq per mL) has been shown. SEM, XRF, and EDS spectroscopy confirm the chemical resistance of 4As-TiO₂ during regeneration. According to the study with ⁹⁰Sr, the decrease in the adsorption capacity of 4As-TiO₂ during regeneration is associated with incomplete leaching of strontium from 4As-TiO₂ micropores. Using an electron accelerator, the radiation resistance of titanium dioxide with surface arsenate groups to β^- -particles with an energy of 1 MeV has been studied. The invariability of the elemental composition and adsorption properties of 4As-TiO₂ at irradiation doses of 5·10⁷Sv testifies to the high radiation resistance of 4As-TiO₂. The result obtained indicates the promise of 4As-TiO₂ for improving radiochemical methods.

Keywords: (90)Sr; Adsorption; Chemical stability; Oxalate technique; Radiation resistance; Titanium dioxide.