High Sensitivity Monitoring of VOCs in Air through FTIR Spectroscopy Using a Multipass Gas Cell Setup

Sensors (Basel). 2022 Jul 27;22(15):5624. doi: 10.3390/s22155624.

Abstract

Human exposure to Volatile Organic Compounds (VOCs) and their presence in indoor and working environments is recognized as a serious health risk, causing impairments of varying severities. Different detecting systems able to monitor VOCs are available in the market; however, they have significant limitations for both sensitivity and chemical discrimination capability. During the last years we studied systematically the use of Fourier Transform Infrared (FTIR) spectroscopy as an alternative, powerful tool for quantifying VOCs in air. We calibrated the method for a set of compounds (styrene, acetone, ethanol and isopropanol) by using both laboratory and portable infrared spectrometers. The aim was to develop a new, and highly sensitive sensor system for VOCs monitoring. In this paper, we improved the setup performance, testing the feasibility of using a multipass cell with the aim of extending the sensitivity of our system down to the part per million (ppm) level. Considering that multipass cells are now also available for portable instruments, this study opens the road for the design of new high-resolution devices for environmental monitoring.

Keywords: FTIR; VOCs; accuracy; acetone; ethanol; isopropanol; ppmv; sensor; styrene.

MeSH terms

  • Air Pollutants* / analysis
  • Air Pollution, Indoor* / analysis
  • Environmental Monitoring / methods
  • Humans
  • Spectroscopy, Fourier Transform Infrared
  • Volatile Organic Compounds* / analysis

Substances

  • Air Pollutants
  • Volatile Organic Compounds

Grants and funding

This research was supported by the Ph. D. funding in the framework of Programma Operativo Nazionale (PON)—Ricerca e Innovazione 2014–2020—Azione IV.5-Dottorati su tematiche green. We thank for funding BRIC-INAIL project ID 07/2019; NATO Science for Peace and Security Programme under grant No. G5889—“SARS-CoV-2 Multi-Messenger Monitoring for Occupational Health & Safety-SARS 3M”, LazioInnova “Gruppi di Ricerca 2020” of the POR FESR 2014/2020-A0375-2020-36651 project entitled “DEUPAS -DEterminazione Ultrasensibile di agenti PAtogeni mediante Spettroscopia”. Financial support by the Grant to Department of Science, Roma Tre University (MIUR-Italy Dipartimenti di Eccellenza, ARTICOLO 1, COMMI 314-337 LEGGE 232/2016) is gratefully acknowledged.