The hazardous nature of certain azeotropic mixtures has urged the researchers to explore the separation techniques which can impart a contamination free environment. Despite of causing environmental concerns, these azeotropic mixtures are responsible for causing serious health issues to humans and animals. More specifically, in this article, we have taken Tetrahydrofuran (THF) - water azeotropic mixture into consideration. It has been reported that it affects the central nervous system, liver, as well as can cause carcinogenicity. To be more precise, in this article, two different entrainers has been evaluated on their merits of exploiting liquid-liquid phase envelope for separating Tetrahydrofuran-water binary azeotropic mixture. The process flow sheet schematic with n-octane as entrainer (having two distillation regions) has a reduced operating energy requirement by 21.11% while comparing with the Residue Curve Map of n-hexane as entrainer having three distillation regions. The total capital cost for THF-water-n-octane case has been found to be 7.1 $/y × 105 and that of THF-water-n-hexane case has been found to be 9 $/y × 105. However, in both of the cases, the product purity of 99.9% has been achieved for THF. Also, the classical trade-off between capital cost and energy cost has been shown in this study. The salient feature of this work is the use of dynamic simulation to understand the effect of recycle flow rate induced process operational in-feasibility due to distillation region shift.
Keywords: Azeotropes; Control structure; Distillation regions; Hazardous effluent; Liquid-liquid phase envelope; Process flow sheet design.
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