Nanopatterning of Perovskite Thin Films for Enhanced and Directional Light Emission

ACS Appl Mater Interfaces. 2022 Aug 24;14(33):38067-38076. doi: 10.1021/acsami.2c09643. Epub 2022 Aug 9.

Abstract

Lead-halide perovskites offer excellent properties for lighting and display applications. Nanopatterning perovskite films could enable perovskite-based devices with designer properties, increasing their performance and adding novel functionalities. We demonstrate the potential of nanopatterning for achieving light emission of a perovskite film into a specific angular range by introducing periodic sol-gel structures between the injection and emissive layer by using substrate conformal imprint lithography (SCIL). Structural and optical characterization reveals that the emission is funnelled into a well-defined angular range by optical resonances, while the emission wavelength and the structural properties of the perovskite film are preserved. The results demonstrate a flexible and scalable approach to the patterning of perovskite layers, paving the way toward perovskite LEDs with designer angular emission patterns.

Keywords: directional emission; halide perovskite; light emitting diodes; light outcoupling; nanoimprint; nanopattern; waveguiding modes.