Pulsed-sonochemiluminescence combined with molecularly imprinted polymerized high internal phase emulsion adsorbent for determination of bentazone

Abstract

A small low-power humidifier with a simple programmable on/off switch was used as a pulsed ultrasound generator. Using this tool, a novel sonochemiluminescence (SCL) method was developed to determine bentazone. To the best of our knowledge, no chemiluminescence method has been proposed to determine this pesticide. Only five studies have been proposed for SCL quantitative applications so far. Therefore, revealing new aspects of SCL promises to develop analytical methods for the quantitative determination of different substances. A molecularly imprinted polymerized high internal phase emulsion (MIP-polyHIPE) was synthesized, bentazone separated from aqueous solutions, and pre-concentrated by the MIP-polyHIPE foam. The adsorption of bentazone on the MIP-polyHIPE adsorbent was theoretically studied by density functional theory through molecular dynamics simulation. Both experimental and simulation results indicated removal and pre-concentration of bentazone by the MIP-polyHIPE adsorbent. Using the proposed SCL method and without pre-concentration process, a linear dynamic range (LDR) of 2.5 × 10^-7-5.0 × 10^-5 mol L^-1 and a limit of detection (LOD) of 8.4 × 10^-8 mol L^-1 were obtained for bentazone with a relative standard deviation of 2.64%. The LDR and LOD were improved to 2.6 × 10^-9-2.0 × 10^-7 mol L^-1 and 8.8 × 10^-10 mol L^-1, respectively, using MIP-polyHIPE adsorbents. The method's application was evaluated by removing and pre-concentration of bentazone from water samples, including well, river, and tap water. The results showed that the pre-concentration factor and recovery percentages were 113-131 times and 93-106%, respectively, using the MIP-polyHIPE absorbent.

Keywords: Bentazone; Density functional theory; High internal phase emulsion adsorbents; Molecular dynamics simulation; Molecularly imprinted polymer; Sonochemiluminescence.