Nano-modification of carboxylated polyether for enhanced room temperature demulsification of oil-water emulsions: Synthesis, performance and mechanisms

Jingjing Zhou; Xincheng Zhang; Lin He; Hong Sui; Xingang Li

doi:10.1016/j.jhazmat.2022.129654

Nano-modification of carboxylated polyether for enhanced room temperature demulsification of oil-water emulsions: Synthesis, performance and mechanisms

J Hazard Mater. 2022 Oct 5:439:129654. doi: 10.1016/j.jhazmat.2022.129654. Epub 2022 Jul 21.

Authors

Jingjing Zhou¹, Xincheng Zhang¹, Lin He², Hong Sui³, Xingang Li⁴

Affiliations

¹ School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China; National Engineering Research Centre of Distillation Technology, Tianjin 300072, China.
² School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China; National Engineering Research Centre of Distillation Technology, Tianjin 300072, China; Zhejiang Institute of Tianjin University, Ningbo, Zhejiang 315201, China. Electronic address: linhe@tju.edu.cn.
³ School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China; National Engineering Research Centre of Distillation Technology, Tianjin 300072, China. Electronic address: suihong@tju.edu.cn.
⁴ School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China; National Engineering Research Centre of Distillation Technology, Tianjin 300072, China; Zhejiang Institute of Tianjin University, Ningbo, Zhejiang 315201, China.

PMID: 35908401
DOI: 10.1016/j.jhazmat.2022.129654

Abstract

Oil-water emulsions separation is frequently required considering the production and environmental issues. Herein, a nano-modification strategy has been proposed for carboxylated poly(propylene oxide)-poly(ethylene oxide) block polyether (mANP) using epoxy-functionalized magnetic nanoparticles (Fe₃O₄@SiO₂-GPTMS), achieving the construction of a highly efficient demulsifier (M-mANP). Bottle tests showed that M-mANP could separate over 98.5% of water from the asphaltene-stabilized water-in-oil (W/O) emulsion at mANP concentration of 150 ppm within 2 min at room temperature. The demulsification efficiency for crude oil-in-water emulsion was nearly 100%. According to interfacial tension and wettability tests, the nano-modification endows M-mANP with good amphiphilicity and high interfacial activity, which enables M-mANP to rapidly adsorb at the oil-water interface. Molecular dynamics simulation shows that abundant oxygen-containing groups (hydroxyl, ether bond, ester and carboxyl groups, Fe-O and Si-O bond) in M-mANP could strengthen the interaction with water, facilitating the replacement of asphaltene molecules at interfacial film. Observation of demulsification process by microscope reveals that the nano-size promotes M-mANP to bridge small dispersed droplets, enhancing the flocculation and coalescence of droplets. The nano-modified carboxylated polyether with outstanding demulsification ability shows a promising application for the treatment of different oil-water emulsions.

Keywords: Block polyether; Demulsification; Magnetic nanoparticles; Molecular dynamics simulation; Nano-modification.