Quartz-Enhanced Photothermal Spectroscopy-Based Methane Detection in an Anti-Resonant Hollow-Core Fiber

Sensors (Basel). 2022 Jul 23;22(15):5504. doi: 10.3390/s22155504.

Abstract

In this paper, the combination of using an anti-resonant hollow-core fiber (ARHCF), working as a gas absorption cell, and an inexpensive, commercially available watch quartz tuning fork (QTF), acting as a detector in the quartz-enhanced photothermal spectroscopy (QEPTS) sensor configuration is demonstrated. The proof-of-concept experiment involved the detection of methane (CH4) at 1651 nm (6057 cm-1). The advantage of the high QTF Q-factor combined with a specially designed low-noise amplifier and additional wavelength modulation spectroscopy with the second harmonic (2f-WMS) method of signal analysis, resulted in achieving a normalized noise-equivalent absorption (NNEA) at the level of 1.34 × 10-10 and 2.04 × 10-11 W cm-1 Hz-1/2 for 1 and 100 s of integration time, respectively. Results obtained in that relatively non-complex sensor setup show great potential for further development of cost-optimized and miniaturized gas detectors, taking advantage of the combination of ARHCF-based absorption cells and QTF-aided spectroscopic signal retrieval methods.

Keywords: anti-resonant hollow-core fiber (ARHCF); quartz tuning fork; quartz-enhanced photothermal spectroscopy (QEPTS).

MeSH terms

  • Amplifiers, Electronic
  • Methane*
  • Proof of Concept Study
  • Quartz*
  • Spectrum Analysis / methods

Substances

  • Quartz
  • Methane