Position-Sensitive Bulk and Surface Element Analysis of Decorated Porcelain Artifacts

Materials (Basel). 2022 Jul 22;15(15):5106. doi: 10.3390/ma15155106.

Abstract

Non-destructive characterization of decorated porcelain artifacts requires the joint use of surface-analytical methods for the decorative surface pattern and methods of high penetration depth for bulk-representative chemical composition. In this research, we used position-sensitive X-ray Fluorescence Spectrometry (XRF) and Prompt-gamma activation analysis (PGAA) for these purposes, assisted by 3D structured-light optical scanning and dual-energy X-ray radiography. The proper combination of the near-surface and bulk element composition data can shed light on raw material use and manufacturing technology of ceramics.

Keywords: Prompt-gamma activation analysis; X-ray Fluorescence Spectrometry; non-destructive composition; porcelain.