The three-dimensional (3D) carbon nanostructures/foams are commonly used as active materials for the high-performance flexible piezoresistive sensors due to their superior properties. However, the intrinsic brittleness and poor sensing properties of monolithic carbon material still limits its application. Rational design of the microstructure is an attractive approach to achieve piezoresistive material with superior mechanical and sensing properties, simultaneously. Herein, we introduce novel three-dimensional buckling carbon nanofibers (3D BCNFs) that feature a unique serpentine-buckling microstructure. The obtained 3D BCNFs exhibit superior mechanical properties, including super-elasticity (recovery speed up to 950 mm s-1), excellent flexibility (multiple folds), high compressibility (compressed by 90%), and high fatigue resistance (10,000 bending cycles). The pressure sensor fabricated by the 3D BCNFs shows a high sensitivity of 714.4 kPa-1, a fast response time of 23 ms, and a broad measuring range of 120 kPa. The pressure sensor is further applied to monitor the physiological signals of humans, and is capable of detecting the characteristic pulse waves from the radial artery, fingertip artery, and human-breath, respectively.
Keywords: 3D buckling carbon nanofibers; flexible piezoresistive sensor; mechanical property; piezoresistive sensitivity.