Stability Study of the Irradiated Poly(lactic acid)/Styrene Isoprene Styrene Reinforced with Silica Nanoparticles

Ana Maria Lupu Luchian; Marius Mariş; Traian Zaharescu; Virgil Emanuel Marinescu; Horia Iovu

doi:10.3390/ma15145080

Stability Study of the Irradiated Poly(lactic acid)/Styrene Isoprene Styrene Reinforced with Silica Nanoparticles

Materials (Basel). 2022 Jul 21;15(14):5080. doi: 10.3390/ma15145080.

Authors

Ana Maria Lupu Luchian^{1

2}, Marius Mariş³, Traian Zaharescu⁴, Virgil Emanuel Marinescu⁴, Horia Iovu^{1

5}

Affiliations

¹ Advanced Polymer Materials Group, University Politehnica of Bucharest, 011061 Bucharest, Romania.
² Extreme Light Infrastructure-Nuclear Physics (ELI-NP), Horia Hulubei National Institute for Physics and Nuclear Engineering (IFIN-HH), 077125 Magurele, Romania.
³ Dental Medicine Faculty, University Titu Maiorescu, 22 Dâmbovnicului Tineretului St., 040441 Bucharest, Romania.
⁴ INCDIE ICPE CA, Radiochemistry Center, 313 Splaiul Unirii, 030138 Bucharest, Romania.
⁵ Academy of Romanian Scientists, 050094 Bucharest, Romania.

Abstract

In this paper, the stability improvement of poly(lactic acid) (PLA)/styrene-isoprene block copolymer (SIS) loaded with silica nanoparticles is characterized. The protection efficiency in the material of thermal stability is mainly studied by means of high accurate isothermal and nonisothermal chemiluminescence procedures. The oxidation induction times obtained in the isothermal CL determinations increase from 45 min to 312 min as the polymer is free of silica or the filler loading is about 10%, respectively. The nonisothermal measurements reveal the values of onset oxidation temperatures with about 15% when the concentration of SiO₂ particles is enhanced from none to 10%. The curing assay and Charlesby-Pinner representation as well as the modifications that occurred in the FTIR carbonyl band at 1745 cm^-1 are appropriate proofs for the delay of oxidation in hybrid samples. The improved efficiency of silica during the accelerated degradation of PLA/SIS 30/n-SiO₂ composites is demonstrated by means of the increased values of activation energy in correlation with the augmentation of silica loading. While the pristine material is modified by the addition of 10% silica nanoparticles, the activation energy grows from 55 kJ mol^-1 to 74 kJ mol^-1 for nonirradiated samples and from 47 kJ mol^-1 to 76 kJ mol^-1 for γ-processed material at 25 kGy. The stabilizer features are associated with silica nanoparticles due to the protection of fragments generated by the scission of hydrocarbon structure of SIS, the minor component, whose degradation fragments are early converted into hydroperoxides rather than influencing depolymerization in the PLA phase. The reduction of the transmission values concerning the growing reinforcement is evidence of the capacity of SiO₂ to minimize the changes in polymers subjected to high energy sterilization. The silica loading of 10 wt% may be considered a proper solution for attaining an extended lifespan under the accelerated degradation caused by the intense transfer of energy, such as radiation processing on the polymer hybrid.

Keywords: PLA; SIS; chemiluminescence; silica nanocomposite; stability.

Grants and funding

This research received no external funding.