In the present work, saline leachate of the Bushehr coastal city (Iran) was purified using the ultraviolet/ultrasonication wave/periodate process. The initial TDS and TOC values of the leachate studied were 7390 mg/L and 975 mg/L, respectively. During the effect of various parameters on leachate purification, the experiments were optimized at pH 3, oxidizer concentration of 4 mM, and treatment time of 120 min. The initial BOD5/COD ratio of 0.66 was reduced to 0.42 at the end of the purification time (120 min). After leachate treatment under optimal conditions, the amount of BOD5, COD, and UV254 were 451.5 mg/L, 1072 mg/L, and 12.69 cm-1, respectively. Concentrations of heavy metals in crude leachate by ICP-OES were checked. Also, the concentration of organic compounds before and after purification was determined using GC-Mass. The leachate purification kinetics followed the first-order model using the designed method. Based on the COD factor, the system energy consumption for leachate treatment was calculated to be 11.4 kWh/m3. The results showed that the system explored (UV/US/IO4-) can effectively purify high salinity waste leachate.
Keywords: Humic acids; Leachate; Organic compound; UV254; Ultrasonication wave.
© 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.