The quality of crude palm oil (CPO) is generally determined by the levels of free fatty acids (FFA). This helps in balancing the level of acidity during transportation and storage processes. However, high FFA in CPO is not good for consumer health. One of the methods for adsorbing FFA is adsorption, which is the adhesion of atoms, ions, or molecules from a gas, liquid, or dissolved solid to a surface. Therefore, this study aims to analyze the effect of contact time (40, 80 and 120 min) and Coconut Coir (CC) bioadsorbent concentrations of 1, 2 and 3 (%, w/v) on the reduction of CPO FFA levels. This began with the activation of CC biochar synthesis by using NaOH and HCl, which produced CC-NaOH and CC-HCl bioadsorbents based on the product of NaOH. Furthermore, the adsorption process was carried out by mixing CPO with CC-NaOH and CC-HCl bioadsorbents in a three-necked flask. After this, the filtrate product was obtained and analyzed for its FFA levels. The results showed that the largest percentage reduction for the effect of bioadsorbent concentration was 3% (w/v) at a contact time of 120 min. It also indicated that this study enabled lower levels of FFA in CPO. Based on the detailed cost estimate, the production cost of the CC-NaOH bioadsorbent was USD 481,874, sold at USD 95/ton with annual sales and net profit (after tax) at USD 684,000 and USD 141,188, respectively. This profit after tax and rate of return on investment was found to be 20.68 and 39.49% of the entire estimation, respectively. It also had a payback period of 2.95 years and a break-even point at a capacity of 43.16%. In addition, the prepared adsorbent showed significant ability as an inexpensive, reproducible and environmentally friendly compound used in reducing the FFA levels of CPO.
Keywords: Adsorption; Bioadsorbent; Coconut coir; Crude palm oil; Free fatty acid.
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