An integrated nanoflower-like MoS2@CuCo2O4 heterostructure for boosting electrochemical glucose sensing in beverage

Food Chem. 2022 Dec 1:396:133630. doi: 10.1016/j.foodchem.2022.133630. Epub 2022 Jul 6.

Abstract

Excessive glucose in food poses a non-negligible threat to its inherent quality and human health, which makes it imperative to develop a highly sensitive sensor for real-time glucose detection. In this work, an integrated electrochemical glucose sensor based on a nanoflower-like MoS2@CuCo2O4 heterostructure was carefully constructed. Under optimal conditions, the as-fabricated sensor exhibited a high sensitivity of 1,303 μA mM-1 cm-2 over a wide range of 0.5-393.0 μmol/L, accompanied by a low determination limit (0.5 μmol/L) and short response time (2.1 s). The favorable sensing performance of the MoS2@CuCo2O4 nanocomposite-modified electrode in electrochemical analyses was attributed to the introduction of unique nanoflower-like heterostructure and the synergistic effects between MoS2 and CuCo2O4. Furthermore, the satisfactory applicability of this sensor in beverages was confirmed. These results demonstrate that the MoS2@CuCo2O4/GCE may be a promising platform for sensitive monitoring of glucose content in food samples.

Keywords: Beverage; Glucose detection; MoS(2)@CuCo(2)O(4); Non-enzymatic sensor; Synergistic effects.

MeSH terms

  • Beverages
  • Disulfides / chemistry
  • Electrochemical Techniques* / methods
  • Glucose
  • Humans
  • Limit of Detection
  • Molybdenum* / chemistry

Substances

  • Disulfides
  • Molybdenum
  • Glucose