Gaseous elemental Hg (GEM), particulate bound Hg (PBM), and gaseous oxidized Hg (GOM) were monitored at an urban site in Beijing, China during wet seasons (July-November) of 2021. The mean (± standard deviation) GEM, PBM, and GOM concentrations were 3.45 ± 1.27 ng m-3, 48.2 ± 88.6 pg m-3, and 13.7 ± 55.0 pg m-3, respectively. GEM level was stable (generally 3.0-4.0 ng m-3) and the average concentration was about twice that of the background level in Beijing, while the occasionally very high PBM and GOM concentrations (>1000 pg m-3) suggest pollution events. Moreover, GEM, CO, and NO2 exhibit a conspicuous similar diurnal trend with lower values during daytime compared to nighttime under the combined influence of anthropogenic emissions and meteorological factors, and the significantly positive relationship between them indicates that they had similar or common sources. However, the diurnal pattern of reactive Hg (i.e., RM = PBM + GOM) was not pronounced. Both cluster and potential source contribution function analyses show that southern Beijing, Tianjin, as well as central and east Hebei provinces were the dominant source regions for elevated GEM at this monitoring site. The dominant reason for the elevated GEM level (generally >3.5 ng m-3) during pollution event is that majority of air masses originated from the southern polluted regions of this sampling site and traveled at low heights, while the long-range transport of upper clean air masses and continuous high traveling heights were attributed to the low GEM level (<2.0 ng m-3) during clean event. Positive matrix factorization results reveal that regional transport of coal fired air pollutants and local vehicle emissions were the dominant contributors to elevated GEM level, while RM mainly originated from local sources.
Keywords: Air pollutants; Correlation; Meteorological parameters; Sources identification; Speciated atmospheric mercury.
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