In this study, a ratiometric optical fiber dissolved oxygen sensor based on dynamic quenching of fluorescence from a ruthenium complex is reported. Tris(4,7-diphenyl-1,10-phenanthrolin) ruthenium(II) dichloride complex (Ru(dpp)32+) is used as an oxygen-sensitive dye, and semiconductor nanomaterial CdSe/ZnS quantum dots (QDs) are used as a reference dye by mixing the two substances and coating it on the plastic optical fiber end to form a composite sensitive film. The linear relationship between the relative fluorescence intensity of the ruthenium complex and the oxygen concentration is described using the Stern-Volmer equation, and the ruthenium complex doping concentration in the sol-gel film is tuned. The sensor is tested in gaseous oxygen and aqueous solution. The experimental results indicate that the measurement of dissolved oxygen has a lower sensitivity in an aqueous environment than in a gaseous environment. This is due to the uneven distribution of oxygen in aqueous solution and the low solubility of oxygen in water, which results in a small contact area between the ruthenium complex and oxygen in solution, leading to a less-severe fluorescence quenching effect than that in gaseous oxygen. In detecting dissolved oxygen, the sensor has a good linear Stern-Volmer calibration plot from 0 to 18.25 mg/L, the linearity can reach 99.62%, and the sensitivity can reach 0.0310/[O2] unit. The salinity stability, repeatability, and temperature characteristics of the sensor are characterized. The dissolved oxygen sensor investigated in this research could be used in various marine monitoring and environmental protection applications.
Keywords: dissolved oxygen; fluorescence quenching; optical fiber dissolved oxygen sensor; quantum dots; ruthenium complex.