Mechanism of simultaneous lead and chromium removal from contaminated wastewater by a schwertmannite-like mineral

Abstract

In this study, a schwertmannite-like mineral was synthesized for the removal of lead (Pb) and chromium (Cr) from contaminated wastewater. A shaking flask test was performed (150 r/min, 1 h) with FeSO₄·7H₂O, H₂O₂, Na₂SiO₃, and CaCl₂ added for the mineral synthesis reaction. Results show that optimal performance was achieved with the addition of 1.24 g/L FeSO₄·7H₂O, 0.75 g/L H₂O₂, 1.27 g/L Na₂SiO₃, and 0.44 g/L CaCl₂ at a water temperature of 28 °C, with coexisting ion (Na⁺, K⁺, Mg²⁺) concentrations of 1.50 mmol/L and 0.50 mmol/L EDTA as a complexing agent. Under these optimal conditions, maximum Pb and Cr removal rates of 95.08% and 97.99%, respectively, were achieved within the first 1 min of the mineral synthesis reaction, with the synthesis reaction completed by 6 min. The simultaneous removal of Pb and Cr during the schwertmannite-like material synthesis process occurred via electrostatic adsorption and coprecipitation. When the concentration of the complexing agent was increased from 0.75 to 6.03 mmol/L, the Pb removal rate decreased from 71.88 to 35.45%, and the Cr removal rate decreased from 95.13 to 75.07%, showing that Pb and Cr removal exhibited significant levels of inhibition. In contrast, varying reaction temperatures induced no significant differences. The Pb and Cr dissolution rates from Pb/Cr-containing schwertmannite-like minerals were 8.18% and 2.86% after 40 days, respectively. Therefore, the risk of secondary dissolution of heavy metals is small.

Keywords: Chromium; Complexing agent concentration; Schwertmannite-like mineral; Wastewater; Lead.