Temperature-Dependent Electrochemical Stability Window of Bis(trifluoromethanesulfonyl)imide and Bis(fluorosulfonyl)imide Anion Based Ionic Liquids

Kallidanthiyil Chellappan Lethesh; Ahmed Bahaa; Mariam Abdullah; Musbaudeen O Bamgbopa; Rahmat Agung Susantyoko

doi:10.3389/fchem.2022.859304

Temperature-Dependent Electrochemical Stability Window of Bis(trifluoromethanesulfonyl)imide and Bis(fluorosulfonyl)imide Anion Based Ionic Liquids

Front Chem. 2022 Jun 17:10:859304. doi: 10.3389/fchem.2022.859304. eCollection 2022.

Authors

Kallidanthiyil Chellappan Lethesh¹, Ahmed Bahaa¹, Mariam Abdullah¹, Musbaudeen O Bamgbopa¹, Rahmat Agung Susantyoko¹

Affiliation

¹ Research and Development Centre, Dubai Electricity and Water Authority (DEWA), Dubai, United Arab Emirates.

Abstract

The electrochemical stability of 22 commercially available hydrophobic ionic liquids was measured at different temperatures (288.15, 298.15, 313.15, 333.15 and 358.15 K), to systematically investigate ionic liquids towards electrolytes for supercapacitors in harsh weather conditions. Bis(trifluoromethanesulfonyl)imide and bis(fluorosulfonyl)imide anions in combination with 1-Butyl-1-methylpyrrolidinium, 1-Ethyl-3-methylimidazolium, N-Ethyl-N, N-dimethyl-N(2methoxyethyl)ammonium, 1-Methyl-1-(2-methoxyethyl)pyrrolidinium, N-Pentyl-N-methylpyrrolidinium, N, N-Diethyl-N-methyl-N-propylammonium, N, N-Dimethyl-N-ethyl-N-benzyl ammonium, N, N-Dimethyl-N-Ethyl-N-phenylethylammonium, N-Butyl-N-methylpiperidinium, 1-Methyl-1-propylpiperidinium, N-Tributyl-N-methylammonium, N-Trimethyl-N-butylammonium, N-Trimethyl-N-butylammonium, N-Trimethyl-N-propylammonium, N-Propyl-N-methylpyrrolidinium cations were selected for the study. Linear regression with a numerical model was used in combination with voltammetry experiments to deduce the temperature sensitivity of both anodic and cathodic potential limits (defining the electrochemical stability window), in addition to extrapolating results to 283.15 and 363.15 K. We evaluated the influence of the cations, anions, and the presence of functional groups on the observed electrochemical stability window which ranged from 4.1 to 6.1 V.

Keywords: FSI; TFSI; bis(fluorosulfonyl)imide; bis(trifluoromethanesulfonyl)imide; electrochemical stability; ionic liquids; linear regression; temperature.