Nanoengineered metal-organic framework for adsorptive and photocatalytic mitigation of pharmaceuticals and pesticide from wastewater

Abstract

Rapidly expanding water pollution has transformed into significant dangers around the world. In recent years, the pharmaceutical and agriculture field attained enormous progress to meet the necessities of health and life; however, discharge of trace amounts of pharmaceuticals and pesticides into water significantly have a negative influence on human health and the environment. Contamination with these pollutants also constitutes a great threat to the aquatic ecosystem. To deal with the harmful impacts of such pollutants, their expulsion has attracted researchers' interest a lot, and it became essential to figure out techniques suitable for the removal of these pollutants. Thus, many researchers have devoted their efforts to improving the existing technology or providing an alternative strategy to solve this environmental problem. One of the attractive materials for this purpose is metal-organic frameworks (MOFs) due to their superior high surface area, high porosity, and the tunable features of their structures and function. Among various techniques of wastewater treatment, such as biological treatment, advanced oxidation process and membrane technologies, etc., metal-organic frameworks (MOFs) materials are tailorable porous architectures and are viably used as adsorbents or photocatalysts for wastewater treatment due to their porosity, tunable internal structure, and large surface area. MOFs are synthesized by various methods such as solvo/hydrothermal, sonochemical, microwave and mechanochemical methods. Most common method used for the synthesis of MOFs is solvothermal/hydrothermal methods. Herein, this review aims at providing a comprehensive overview of the latest advances in MOFs and their derivatives, focusing on the following aspects: synthesis and applications. This review comprehensively highlights the application of MOFs and nano-MOFs to remove pharmaceuticals and pesticides from wastewater. For the past years, transition metal-based MOFs have been concentrated as photocatalyst/adsorbents in treating contaminated water. However, work on main group metal-based MOFs is not so abundant. Hence, the foremost objective of this review is to present the latest material and references concerning main group element-based MOFs and nanoscale materials derived from them towards wastewater treatment. It summarizes the possible research challenges and directions for MOFs and their derivatives as catalysts applied to wastewater treatment in the future. With the context of recent pioneering studies on main group elements-based MOFs and their derivatives; we hope to stimulate some possibilities for further development, challenges and future perspectives in this field have been highlighted.

Keywords: Adsorption; Environmental pollutants; Metal-organic frameworks; Pesticides; Pharmaceutical waste; Photocatalysis; Wastewater treatment.