Deep eutectic solvents coupled with (NH4)3H6CoMo6O24 trigger aerobic oxidation of 5-hydroxymethylfurfural to 5-formyl-2-furancarboxylic acid

Yanbin Sun; Kaixuan Yang; Zhiguo Zhu; Ting Su; Wanzhong Ren; Hongying Lü

doi:10.1039/d2cc02544b

Deep eutectic solvents coupled with (NH₄)₃H₆CoMo₆O₂₄ trigger aerobic oxidation of 5-hydroxymethylfurfural to 5-formyl-2-furancarboxylic acid

Chem Commun (Camb). 2022 Jul 19;58(58):8105-8108. doi: 10.1039/d2cc02544b.

Authors

Yanbin Sun¹, Kaixuan Yang¹, Zhiguo Zhu¹, Ting Su¹, Wanzhong Ren¹, Hongying Lü¹

Affiliation

¹ College of Chemistry and Chemical Engineering, Yantai University, Yantai, 264005, Shandong, China. hylv@ytu.edu.cn.

PMID: 35770664
DOI: 10.1039/d2cc02544b

Abstract

An Anderson-type polyoxometalate (NH₄)₃H₆CoMo₆O₂₄ in deep eutectic solvents exhibited outstanding catalytic performance for the selective aerobic oxidation of HMF to FFCA. It is potentially a promising and highly environmentally friendly approach for biomass conversion.

MeSH terms

Acids
Anions
Deep Eutectic Solvents*
Furaldehyde* / analogs & derivatives
Furans
Polyelectrolytes
Solvents

Substances

Acids
Anions
Deep Eutectic Solvents
Furans
Polyelectrolytes
Solvents
polyoxometalate
5-hydroxymethylfurfural
Furaldehyde
2-furoic acid