It was recently reported that the most popular electron-accepting units introduced to π-conjugated oligomers studied for organic photovoltaic applications are susceptible to unwanted and even destructive photochemical reactions. The consequences of Z/E photoisomerization of the popular 2-(1,1-dicyanomethylene)rhodanine (RCN) unit on the optical and morphological properties of a homologous series of RCN-functionalized oligothiophenes are studied here. Oligomers consisting of one, two, or three thiophene units were studied as pure Z isomers and with E isomer compositions of 25, 53, and 45%, respectively, for Z/E mixtures. Solutions of Z isomers and Z/E mixtures were characterized by UV-vis and photoluminescence spectroscopy, wherein changes to optical properties were evaluated on the basis of E isomer content. X-ray diffraction of thin-film Z/E mixtures reveals crystalline domains of both Z and E forms after thermal annealing for mono- and bithiophene oligomers, with greater interplanar spacing for E crystalline domains than the Z counterparts along the substrate normal direction. The surface morphology viewed by atomic force microscopy also shows fiberlike structures for the E form with a much larger aspect ratio than for the Z domains in the bithiophene oligomer. Optical characterization reveals drastic changes in the solid state upon introduction of the E form for the mono- and bithiophene derivatives, whereas subtle consequences are noted for the terthiophene analogue. Most notably, a 132 nm redshift in maximum absorption occurs for the bithiophene oligomer films containing 53% E isomer compared to the pure Z counterpart. Finally, although solid-state photoisomerization experiments find no evidence of Z → E isomerization in polycrystalline Z films, E → Z isomerization is observed and becomes more restrictive in films with higher crystallinity (i.e., after thermal annealing). This structure-property study, which elucidates the consequences of the RCN configuration on solid-state packing and optical properties, is expected to guide the development of more efficient and stable organic optoelectronic devices.
Keywords: conjugated molecules; dicyanorhodanine; donor−acceptor oligomers; optoelectronic properties; organic photovoltaics; photoisomerization.