New directions in radical carbonylation chemistry: combination with electron catalysis, photocatalysis and ring-opening

Takuji Kawamoto; Takahide Fukuyama; Baptiste Picard; Ilhyong Ryu

doi:10.1039/d2cc02700c

New directions in radical carbonylation chemistry: combination with electron catalysis, photocatalysis and ring-opening

Chem Commun (Camb). 2022 Jul 7;58(55):7608-7617. doi: 10.1039/d2cc02700c.

Authors

Takuji Kawamoto¹, Takahide Fukuyama², Baptiste Picard³, Ilhyong Ryu^{3

4}

Affiliations

¹ Department of Applied Chemistry, Yamaguchi University, Ube, Yamaguchi, 755-8611, Japan.
² Department of Chemistry, Osaka Metropolitan University (OMU), Sakai, Osaka, 599-8531, Japan.
³ Organization for Research Promotion, Osaka Metropolitan University (OMU), Sakai, Osaka, 599-8531, Japan. ryu@omu.ac.jp.
⁴ Department of Applied Chemistry, National Yang Ming Chiao Tung University (NYCU), Hsinchu, 30010, Taiwan.

PMID: 35758516
DOI: 10.1039/d2cc02700c

Abstract

Radical carbonylation offers potent methods for introducing carbon monoxide into organic molecules. This feature article focuses on our current efforts to develop new strategies for radical carbonylation, which include electron-transfer carbonylation, site-selective C(sp³)-H carbonylation by a photocatalyst and ring-opening carbonylation.

Publication types

Review

MeSH terms

Carbon Monoxide*
Catalysis
Electron Transport
Electrons*

Substances

Carbon Monoxide