Construction of an ultra-small hydrazone-linked covalent organic polymer for selective fluorescent detection of ferric ion in aqueous solution

Abstract

A novel ultra-small hydrazone-linked covalent organic polymer (UHCOP) was synthesized based on the Schiff-base reaction between 2,4,6-trihydroxy-1,3,5-benzenetricarbaldehyde and 1,4-benzenedicarbohydrazide at room temperature and utilized as a sensitive fluorescent sensor for rapid (<2 min) and selective detection of Fe³⁺ in aqueous solution. The prepared UHCOP displayed ultra-small size with the diameter of 7.98 ± 0.97 nm and gave a stable fluorescent emission at 510 nm. UHCOP exhibited good sensitivity and highly selectivity towards Fe³⁺. The coordination interaction between UHCOP and Fe³⁺ resulted in the obviously aggregation-caused quenching response of UHCOP. The linear range was from 5.0 μM to 1.4 mM (R² = 0.999) with the detection limit of 2.5 μM. Finally, UHCOP has been successfully applied in the detection of Fe³⁺ in real water samples, proving the fabricated UHCOP is promising as a sensitive fluorescent sensor for selective detection of Fe³⁺ in aqueous solution.

Keywords: Aqueous solution; Schiff-base reaction; Selective detection of Fe(3+); Ultra-small hydrazone-linked covalent organic polymer.