Spectroscopy and chromaticity characterization of yellow to light-blue iron-containing beryl

Yanran Shang; Ying Guo; Jun Tang

doi:10.1038/s41598-022-11916-z

Spectroscopy and chromaticity characterization of yellow to light-blue iron-containing beryl

Sci Rep. 2022 Jun 24;12(1):10765. doi: 10.1038/s41598-022-11916-z.

Authors

Yanran Shang¹, Ying Guo², Jun Tang¹

Affiliations

¹ School of Gemmology, China University of Geosciences (Beijing), No.29 Xueyuan Road, Beijing, 100083, China.
² School of Gemmology, China University of Geosciences (Beijing), No.29 Xueyuan Road, Beijing, 100083, China. guoying@cugb.edu.cn.

Abstract

The chemical composition and influencing factors of the colour of 95 yellow to light blue iron-bearing beryl are studied through Electron Microprobe Analysis (EMPA), Energy-dispersive X-ray fluorescence (ED-XRF) spectroscopy, Fourier transform infrared (FTIR) spectroscopy, ultraviolet-visible (UV-vis) spectroscopy and X-Rite SP62 spectrophotometer. The intensities of the three characteristic hydroxyl stretching bands of the beryl from 3500 cm^-1 to 3800 cm^-1 prove they are low to medium levels of alkali bearing natural beryl. The wide absorption edge of 320 ~ 465 nm caused by the ultra-violet charge transfer from O^2- to Fe³⁺ and the 650 nm absorption band in E//c-polarization caused by the intervalence charge transfer between Fe²⁺ and Fe³⁺ are the main factors affecting the colour of beryl. By applying CIE D₆₅ standard light source and N9 Munsell neutral background as testing conditions, the colour parameters of 82 gem-quality beryl are tested. According to the results, iron-containing beryl colours are classified into yellow, yellowish-green, bluish-green, greenish-blue, and blue by the K-means cluster analysis method. The blue tone has a greater influence on the hue of beryl, while the yellow tone has a greater influence on the chroma. Iron content is higher in yellow and blue beryl. With the increase of iron content, the lightness of beryl decreased and the chroma increased.