Terminal-fluoride-coordinated air-stable chiral dysprosium single-molecule magnets

Jinjiang Wu; Guo-Lu Wang; Zhenhua Zhu; Chen Zhao; Xiao-Lei Li; Yi-Quan Zhang; Jinkui Tang

doi:10.1039/d2cc02570a

Terminal-fluoride-coordinated air-stable chiral dysprosium single-molecule magnets

Chem Commun (Camb). 2022 Jul 7;58(55):7638-7641. doi: 10.1039/d2cc02570a.

Authors

Jinjiang Wu^{1

2}, Guo-Lu Wang³, Zhenhua Zhu^{1

4}, Chen Zhao^{1

2}, Xiao-Lei Li¹, Yi-Quan Zhang³, Jinkui Tang^{1

2}

Affiliations

¹ State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China. tang@ciac.ac.cn.
² School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, P. R. China.
³ Jiangsu Key Lab for NSLSCS, School of Physical Science and Technology, Nanjing Normal University, Nanjing 210023, P. R. China. zhangyiquan@njnu.edu.cn.
⁴ University of Chinese Academy of Sciences, Beijing 100049, P. R. China.

PMID: 35723250
DOI: 10.1039/d2cc02570a

Abstract

Terminal fluoride ligands generate strong magnetic anisotropy in air-stable chiral dysprosium enantiomers supported by a bulky equatorial macrocycle, exhibiting a typical zero-field single-molecule magnet behaviour.