Micropancake, a flat domain with micrometer-scale lateral size and a few nanometer thickness, is usually accompanied by the generation of interfacial nanobubbles at the liquid/solid surfaces. Unlike the nanobubbles, micropancakes are difficult to be produced efficiently, impeding further investigations of their mysterious properties. Very recently, An et al. even argued that the previously observed micropancakes were most likely the contaminate, not the gas layers. Herein, to reveal the nature of micropancakes with solid evidence, we presented the in situ characterization of micropancakes at a highly oriented pyrolytic graphite (HOPG) surface produced by the ethanol-water exchange or gas-supersaturated water. By washing with deeply degassed water (DW), the dissolution of those micropancakes was clearly observed, indicating that they may very well be composed of gas. In addition, the analysis of the force measurements showed the intrinsic differences between those gaseous micropancakes and the insoluble organic films. The data and results supported the interpretation that the real existence of gas micropancakes at liquid/solid surfaces.